前言Chapter 1 Basic Knowledge of Analytical Chemistry Experiments 1.1 Basic Requirements for Analytical Chemistry Experiments 1.2 Basic Knowledge of the LaboratoryChapter 2 Basic Operation for Quantitative Analysis 2.1 Analytical Balance 2.2 Pipetting and Constant Volume Operation 2.3 Burette and Basic Operations for Titration Analysis 2.4 Basic Operations of Gravimetric AnalysisChapter 3 Quantitative Analysis Experiments 3.1 Basic Operation Practices Exp.1 Practices of Analytical Balance Exp.2 Practices of Basic Operation for Titration Analysis 3.2 Acid-base Titration Experiments Exp.3 Preparation and Standardization of NaOH Standard Solution Exp.4 Preparation and Standardization of HCl Solution Exp.5 Determination of Boric Acid in Food Additives Exp.6 Analysis of Mixed Alkali Exp.7 Determination of Nitrogen in Ammonium Salts Exp.8 Determination of Total Phosphorus in Phosphate Fertilizer Exp.9 Determination of Total Acidity in Edible Vinegar Exp.10 Determination of the Molar Mass of Organic Acids 3.3 Complexometric Titration Experiments Exp.11 Preparation and Standardization of EDTA Standard Solution and Determination of Water Hardness Exp.12 Determination of Calcium and Magnesium in Industrial Raw Materials Exp.13 Determination of Pb2+ and Bi3+ in Mixture of Pb2+ and Bi3+ Exp.14 Determination of Aluminum and Magnesium in Gastropine Tablet Exp.15 Determination of EDTA in Detergents Exp.16 Determination of Iron, Aluminum, Calcium and Magnesium in Cement Clinker Exp.17 Determination of Aluminum in Industrial Aluminum Sulfate 3.4 Redox Titration Experiments Exp.18 Preparation and Standardization of Potassium Permanganate Standard Solution and Determination of H2O2 Exp.19 Determination of Iron in Iron Ore by Potassium Dichromate Method (Mercury-Free Method) Exp.20 Determination of Chemical Oxygen Demand in Environmental WaterSamples (KMnO4 Method) Exp.21 Determination of Chemical Oxygen Demand in Sewage (K2Cr2O7 Method) Exp.22 Determination of Copper in Copper Salt by Indirect Iodimetry Exp.23 Determination of Calcium in Calcium Preparations Exp.24 Determination of Dissolved Oxygen in Water Exp.25 Determination of Vitamin C in Juice Exp.26 Determination of Glucose in Glucose Injection 3.5 Precipitation Titration and Gravimetric Analysis Experiments Exp.27 Determination of Chlorine in Soluble Chloride by Mohr Method Exp.28 Determination of Chlorine in Soluble Chloride by Vollhard Method Exp.29 Determination of Barium in Barium Salt by Gravimetric Method Exp.30 Determination of Barium in Barium Salts (Microwave Drying Gravimetric Method) Exp.31 Determination of Potassium in Fertilizer Exp.32 Determination of Nickel in SteelChapter 4 Spectrophotometry and Common Separation Methods Experiments Exp.33 Spectrophotometric Determination of Iron with Phenanthroline Exp.34 Determination of NO2– in Food Exp.35 Determination of Available Phosphorus in Soil Exp.36 Determination of Total Flavonoids in Bamboo Leaves by Spectrophotometry Coupled with Microwave-assisted Extraction Technique Exp.37 Determination of Trace Lead in Environmental Water Samples by Extraction Separation-spectrophotometry Exp.38 Separation and Identification of Amino Acids by Paper Chromatography Exp.39 Separation of Food Pigments by Paper ChromatographyChapter 5 Comprehensive Design Experiments 5.1 Acid-base Titration Design Experiments Exp.40 Determination of SiO2 by Potassium Fluosilicate Method Exp.41 Determination of NaHCO3 and Na2CO3 in Biscuits Exp.42 Determination of Boron Trioxide of Slag 5.2 Complexometric Titration Design Experiments Exp.43 Determination of ZnO in Calamine Lotion Exp.44 Determination of Nickel and Magnesium in Nickel-magnesium Alloys Exp.45 Determination of Each Component in Mixture of Mg2+ and EDTA 5.3 Redox Titration Design Experiments Exp.46 Determination of Chromium in Alloys Exp.47 Determination of Iodine in Iodized Salt Exp.48 Determination of Ferrous Oxide in Iron-containing Steel Slag 5.4 Precipitation Titration Design Experiments Exp.49 Determination of Sodium Chlorine in Food Exp.50 Determination of Chloride Ion in Complex Fertilizer Exp.51 Determination of Silver in Nylon Silver-plated Fiber 5.5 Spectrophotometry Design Experiments Exp.52 Determination of Chromium and Manganese in Steel by Spectrophotometry Exp.53 Determination of Trace Chlorine in Air Exp.54 Determination of Lead in Plant Leaves by Spectrophotometry 5.6 Comprehensive Experiments Exp.55 Preparation and Composition Determination of Potassium Copper (Ⅱ) Dioxalate Exp.56 Preparation of Sodium Thiosulfate and Determination of Product Content Exp.57 Determination of Zinc Oxide and Boron Trioxide in Flame RetardantsAppendix Appendix 1 Preparation of Commonly Used Buffer Appendix 2 Commonly Used Indicator Appendix 3 Concentrations and Densities of Common Acid-base Solutions Appendix 4 Common Primary Standard and Their Drying Conditions and Applications Appendix 5 Molecular Weight of Common Compounds第1章 分析化學實驗基本知識 1.1 分析化學實驗的基本要求 1.2 實驗室基本知識第2章 定量分析基本操作 2.1 分析天平 2.2 移液和定容操作 2.3 滴定管及滴定分析基本操作 2.4 重量分析法的基本操作第3章 定量分析實驗 3.1 基礎操作練習 實驗1 分析天平稱量練習 實驗2 滴定分析基本操作練習 3.2 酸堿滴定實驗 實驗3 NaOH標準溶液的配制和標定 實驗4 HCl溶液的配制和標定 實驗5 食品添加劑中硼酸含量的測定 實驗6 混合堿的分析 實驗7 銨鹽中氮含量的測定 實驗8 磷肥中全磷的測定 實驗9 食用醋總酸度的測定 實驗10 有機酸摩爾質量的測定 3.3 絡合滴定實驗 實驗11 EDTA標準溶液的配制、標定和水硬度的測定 實驗12 工業原料中鈣、鎂含量的測定 實驗13 鉛、鉍混合溶液中鉛、鉍含量的測定 實驗14 胃舒平片中鋁和鎂含量的測定 實驗15 洗滌劑中EDTA含量的測定 實驗16 水泥熟料中鐵、鋁、鈣、鎂含量的測定 實驗17 工業硫酸鋁中鋁含量的測定 3.4 氧化還原滴定實驗 實驗18 高錳酸鉀標準溶液的配制、標定和H2O2含量的測定 實驗19 重鉻酸鉀法測定鐵礦石中的鐵含量(無汞法) 實驗20 環境水樣中化學需氧量的測定(KMnO4法) 實驗21 污水中化學需氧量的測定(K2Cr2O7法) 實驗22 間接碘量法測定銅鹽中的銅含量 實驗23 鈣制劑中鈣含量的測定 實驗24 水中溶解氧的測定 實驗25 果汁中維生素C含量的測定 實驗26 葡萄糖注射液中葡萄糖含量的測定 3.5 沉淀滴定及重量分析法實驗 實驗27 莫爾法測定可溶性氯化物中的氯含量 實驗28 福爾哈德法測定可溶性氯化物中的氯含量 實驗29 重量分析法測定鋇鹽中的鋇含量 實驗30 鋇鹽中鋇含量的測定(微波干燥重量法) 實驗31 肥料中鉀含量的測定 實驗32 鋼鐵中鎳含量的測定第4章 分光光度法及常用分離方法實驗 實驗33 鄰二氮菲分光光度法測定鐵 實驗34 食品中NO2-含量的測定 實驗35 土壤中有效磷的測定 實驗36 微波輔助萃取-分光光度法測定竹葉中總黃酮 實驗37 萃取分離-分光光度法測定環境水樣中微量鉛 實驗38 紙色譜法分離和鑒定氨基酸 實驗39 紙色譜法分離食用色素第5章 綜合設計實驗 5.1 酸堿滴定設計實驗 實驗40 氟硅酸鉀法測定SiO2 實驗41 餅干中NaHCO3和Na2CO3含量的測定 實驗42 礦渣中三氧化二硼的測定 5.2 絡合滴定設計實驗 實驗43 爐甘石洗劑中ZnO含量的測定 實驗44 鎳鎂合金中鎳、鎂的測定 實驗45 Mg2+-EDTA混合液中各組分的測定 5.3 氧化還原滴定設計實驗 實驗46 合金中鉻含量的測定 實驗47 加碘食鹽中碘含量的測定 實驗48 含鐵鋼渣中氧化亞鐵含量的測定 5.4 沉淀滴定設計實驗 實驗49 食品中氯化鈉的測定 實驗50 復合肥料中氯離子含量的測定 實驗51 尼龍鍍銀纖維中銀含量的測定 5.5 分光光度法設計實驗 實驗52 分光光度法測定鋼樣中的鉻和錳 實驗53 空氣中微量氯氣的測定 實驗54 分光光度法測定植物葉中的鉛含量 5.6 其他綜合實驗 實驗55 二草酸根合銅(Ⅱ)酸鉀的制備及組成測定 實驗56 硫代硫酸鈉的制備及產物含量的測定 實驗57 阻燃劑中氧化鋅和三氧化二硼的測定附錄 附錄1 常用緩沖溶液的配制 附錄2 常用指示劑 附錄3 常用酸堿溶液的濃度和密度 附錄4 常用基準物質及其干燥條件與應用 附錄5 常用化合物的分子量主要參考文獻